Synthesis of Tunable Syngas on Cobalt-Based Catalysts towards Carbon Dioxide Reduction.
- 影响因子：3.154
- DOI码：10.1002/cnma.202000529
- 发表刊物：ChemNanoMat
- 关键字：Co catalysts, CO2 electroreduction, syngas synthesis, Carbon dioxide, Doping (additives), Electrolytic reduction, Pollution control, Carbon dioxide reduction, Co-existence, Cobalt-based catalysts, Electro reduction, Faradaic efficiencies, Renewable electricity, Reversible hydrogen electrodes, Structural characterization, Synthesis gas
- 摘要：CO2 electroreduction, which coupled the application of renewable electricity, paved a promising way for syngas synthesis. Herein, we demonstrated that Co-based N doped carbon prepared by a simple pyrolysis method provided an ideal platform to generate syngas with tunable ratios of H-2 to CO. During CO2 electroreduction, Co-based N doped carbon exhibited the highest faradaic efficiency (FE) of 56.3% for CO with a total current density of 10.8 mA cm(-2) at -0.9 V versus reversible hydrogen electrode. Structural characterizations showed that the co-existence of Co-0 and Co2+ was responsible for the synthesis of tunable syngas. Notably, we obtained syngas with tunable ratios of H-2 to CO ranging from similar to 1 : 1 to 3 : 1 with the highest current density reaching 47.6 mA cm(-2). This work provides a green way to produce syngas for further applications.
- 合写作者：Xiangdong Kong, Cheng Wang, Zhigang Geng
- 第一作者：Mengke Huang
- 通讯作者：Jie Zeng, Jun Bao
- 文献类型：SCI
- 卷号：7
- 期号：1
- 页面范围：2-6
- 是否译文：否
- 发表时间：2020/11/17
- 发布期刊链接：https://onlinelibrary.wiley.com/doi/abs/10.1002/cnma.202000529
