A phosphate-derived bismuth catalyst with abundant grain boundaries for efficient reduction of CO2 to HCOOH.
- 影响因子：6.222
- DOI码：10.1039/d0cc06756c
- 发表刊物：Chem. Commun.
- 关键字：Bismuth, Bismuth compounds, Catalysts, Electrolytic reduction, Electron emission, Grain boundaries, Catalytic performance, CO2 activation, Electro reduction, Electrochemical transformation, High current densities, Mechanistic studies, Formic acid, carbon dioxide, nanorod, phosphate, adsorption, Article, catalyst, chemical parameters, chemical structure, controlled study, current density, electrochemistry, grain boundary, hydrogen evolution, kinetics, reduction (chemistry), synthesis
- 摘要：Electroreduction of CO2 to HCOOH with high current densities and efficiencies remains a challenge. Herein, we developed a metallic Bi catalyst with abundant grain boundaries through the electrochemical transformation of BiPO4 nanorods to boost the catalytic performance of the electroreduction of CO2 to HCOOH. The phosphate-derived Bi catalyst (PD-Bi) achieved an FE of 91.9% for HCOOH at a high current density of -600.0 mA cm(-2). Mechanistic study revealed that the abundant grain boundaries within PD-Bi promoted the adsorption of CO2 and stabilization of the CO2- intermediate, resulting in facilitated CO2 activation and thus enhanced catalytic performance.
- 合写作者：Huihuang Chen, Yan Liu, Yelin Sheng, Jie Zeng
- 第一作者：Yulin Xing
- 通讯作者：Zhigang Geng, Jun Bao
- 文献类型：SCI
- 卷号：57
- 期号：12
- 页面范围：1502-1505
- 是否译文：否
- 发表时间：2020/12/09
- 发布期刊链接：https://pubs.rsc.org/en/content/articlelanding/2021/CC/D0CC06756C
