CuCo alloy nanonets derived from CuCo2O4 spinel oxides for higher alcohols synthesis from syngas.
- 影响因子：6.119
- DOI码：10.1039/d1cy01179k
- 发表刊物：Catal. Sci. Technol.
- 关键字：Binary alloys
Copper alloys
Phase separation
Surface defects
Calcination method
Catalytic performance
Catalytic results
Cu-co alloys
Higher alcohols synthesis
Hydrothermal-calcination
Nano-net
Spinel oxide
Syn gas
Topological transformation
Synthesis gas
- 摘要：Porous CuCo alloy nanonets were fabricated via structural topological transformation of CuCo2O4 spinel precursors prepared by a facile hydrothermal-calcination method. Their structural properties together with catalytic performance for higher alcohol synthesis (HAS) from syngas were systematically investigated. Characterization results demonstrated that Cu and Co atoms were uniformly distributed in the alloy nanonets without phase separation. Furthermore, the CuCo homogenized alloy nanonets were rich in surface defects, such as grains, steps and pores. The catalytic results of HAS showed that the CuCo alloy nanonets presented a high CO conversion of 66.5%, a C2+OH selectivity in total alcohols of 92.3 wt% and a space time yield (STY) of 228.2 g kgcat-1 h-1 for C2+OH. Compared with CuCo nanoparticle counterparts made by a conventional impregnation method, the CuCo alloy nanonets showed superior catalytic performance toward HAS. This work provides a novel strategy for the rational design of bimetallic alloy catalysts.
- 合写作者：Ruyang Wang, Wenjie Li, Jingyan Wang, Hongliang Li, Yisheng Tan, Jun Bao
Li, W. J.
Wang, J. Y.
Li, H. L.
Tan, Y. S.
- 第一作者：Chao Huang, Peiyu Ma
- 通讯作者：Lei Luo, Xu Li
- 文献类型：SCI
- 卷号：11
- 期号：23
- 页面范围：7617-7623
- 是否译文：否
- 发表时间：2021/10/09
- 发布期刊链接：https://pubs.rsc.org/en/content/articlelanding/2021/CY/D1CY01179K
